Keywords: Peano continuum; Path space; Shape injective; Homotopically Hausdorff; 1-ULC 相似文献
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61.
A. V. Karasev 《Mathematical Notes》1999,66(5):550-555
Under the assumption of the continuum hypothesis, a differentiable 4-manifoldM of dimension dimM=∞ and cohomological dimension cA—dimM=4 is constructed. The spaceM is perfectly normal and hereditarily separable.
Translated fromMatematicheskie Zametki, Vol. 66, No. 5, pp. 664–670, November, 1999. 相似文献
62.
用密度泛函理论方法研究了气相和水溶液中Gd(H2O)n^3+(n=8,9)化合物的结构和相对稳定性,其中水溶剂效应利用极化连续介质方法结合多种溶质空腔模型进行模拟.气相计算得到的化合物结构与实验观察结果一致.计算结果表明,在气相中9配位Gd(H2O)9^3+比8配位Gd(H2O)8^3+稳定,而在水溶液中稳定顺序刚好相反,这一结果不依赖于计算中采用的空腔模型种类,而且也与实验结果吻合.最后,通过采用各种空腔模型计算Gd^3+的水合自由能,并与实验值比较,发现当化合物只包含第一层配位水分子时,UA0、UAHF及UAKS空腔模型最适合研究Gd^3+在水溶液中的性质. 相似文献
63.
G. Conner M. Meilstrup D. Repov A. Zastrow M.
eljko 《Topology and its Applications》2008,155(10):1089-1097
Two natural questions are answered in the negative:
- • “If a space has the property that small nulhomotopic loops bound small nulhomotopies, then are loops which are limits of nulhomotopic loops themselves nulhomotopic?”
• “Can adding arcs to a space cause an essential curve to become nulhomotopic?”
64.
M. Monajjemi M. Khosravi B. Honarparvar F. Mollaamin 《International journal of quantum chemistry》2011,111(12):2771-2777
In this study, quantum chemical calculations using density functional theory and 6‐311G (d) basis set have been applied to analyze the substituent effect on the electronic structural properties including thermochemical parameters as well as anticancer characteristics of catechin as a bioactive constituent of green tea. It has been found out that different substituents with two kinds of electron donating and electron withdrawing groups including ? NO2, ? NH2, ? Cl, ? OCH3, and ? CH3 leaded to different structural stabilities. The catechin with chloro substituents has been referred to the most stable catechin derivatives based on the minimum energy of investigated compounds. In this study, the calculated values have been compared in gas phase and different solvent media with a wide range of solvent dielectrics using the self‐consistent reaction field method with polarizable continuum model. Relative interaction energies between solute and solvent as well as dipole moment values have been analyzed. The results of solvent effect study revealed that the formation of hydrogen bonds accounts for the stabilization of catechin. These calculated data were found to be a logical way in predicting the relative stability of catechin derivatives and can be useful for drug design of anticancer drugs and would open a new door for the researchers who are interested in natural products. The results presented in this article will be helpful to improve existing model and will open up a whole new arena of study to understand the anticancer characteristic of these antioxidant drugs derived from natural products against the photosensitizing DNA damage induce by catechin extracts and enable a much clearer understanding of how anticancer drugs mediate their effects on the specific spot. © 2010 Wiley Periodicals, Inc. Int J Quantum Chem, 2011 相似文献
65.
《Analytical letters》2012,45(16):2467-2481
The content of lead in human hair was measured by high resolution continuum source graphite furnace atomic absorption spectrometry (HR-CS GFAAS) combined with microwave-assisted digestion (MAD) and direct solid sampling (DSS). Hair strands were washed, dried, and then cut into three parts (root, middle portion, and tip). For MAD-GFAAS assays, approximately 0.25 g of hair was completely digested using a mixture of concentrated nitric acid and hydrogen peroxide in a closed system. In the DSS-GFAAS assays, 0.1–0.2 mg of dried hair was directly introduced into a graphite furnace using a solid autosampler. The temperature programs were optimized and the effects of various added modifiers were compared. The results indicated that NH4H2PO4 was the optimal modifier for analysis of Pb using GFAAS. Use of the optimal modifier and temperature program gave similar limits of detection for MAD-GFAAS and DSS-GFAAS of 1.16 ng/g and 0.82 ng/g, respectively. Both methods also produced satisfactory recoveries ranging from 98.69% to 103.14%. There was no significant difference observed between the Pb contents of hair strands determined by the MAD-GFAAS and DSS-GFAAS assays, which both indicated that the Pb levels increased along the hair strands. Comparison of the two methods revealed that DSS-GFAAS had several advantageous characteristics over MAD-GFAAS, including the need for much less sample material and having a less time-consuming procedure, lower sample blank absorbance, lower memory effect, and no risk of environmental pollution by digesting chemicals. The direct solid sampling technique can be employed as a good alternative to conventional wet digestion in AAS assays. 相似文献
66.
We extend a hybrid DSMC/Navier–Stokes (NS) approach to unify the DSMC and the NS simulators in one framework capable of solving the mixed non‐equilibrium and near‐equilibrium flow regions efficiently. Furthermore, we use a one‐way state‐based coupling (Dirichlet–Dirichlet boundary‐condition coupling) to transfer the required information from the continuum region to the rarefied one. The current hybrid DSMC–NS frame is applied to the hypersonic flows over nanoflat plate and microcylinder cases. The achieved solutions are compared with the pure DSMC and NS solutions. The results show that the current hybrid approach predicts the surface heat transfer rate and shear stress magnitudes very accurately. Some important conclusions can be drawn from this study. For example, although the shock wave region would be a non‐equilibrium region, it is not necessary to use a pure DSMC simulator to solve it entirely. This is important when the researchers wish to predict the surface properties such as velocity slip, temperature jump, wall heat flux rate, and friction drag magnitudes accurately. Our investigation showed that our hybrid solution time would be at least 40% (for the flat plate) and 35% (for the cylinder) of the time that must be spent by a pure DSMC solver to attain the same accuracy.Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
67.
In this paper, using the integral method observed by Mai Jiehua recently, we show that no dendrite admits a sensitive commutative group action. 相似文献
68.
We discuss some aspects of the continuum limit of some lattice models, in particular the 2DO(N) models. The continuum limit is taken either in an infinitevolume or in a box whose size is a fixed fraction of the infinite-volume
correlation length. We point out that in this limit the fluctuations of the lattice variables must be O(1) and thus restore
the symmetry which may have been broken by the boundary conditions (b.c.). This is true in particular for the socalled super-instanton
b.c. introduced earlier by us. This observation leads to a criterion to assess how close a certain lattice simulation is to
the continuum limit and can be applied to uncover the true lattice artefacts, present even in the so-called “perfect actions”.
It also shows that David’s recent claim that superinstanton b.c. require a different renormalization must either be incorrect
or an artefact of perturbation theory. 相似文献
69.
V. I. Baranovski E. N. Pisarevskaya O. V. Vinogradova O. V. Sverdlova I. A. Balova 《Russian Chemical Bulletin》2007,56(10):2014-2020
The results of experimental and theoretical investigation of the electronic absorption spectra of substituted phenyldiacethylenes
are presented. The bands in the experimental spectra were assigned in detail using quantum chemical calculations of the electronic
structures and spectra of the molecules. The influence of the interaction of the substituents on the spectral parameters of
the systems under study was analyzed.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1947–1953, October, 2007. 相似文献
70.
An exact three-dimensional analysis is developped for an axisymmetric loading acting on the surface of a semi-infinite medium composed by two transversely isotropic materials. The loading is assumed to be parallel to the elastic symmetry axis of the upper layer. The solutions of a concentrated force and a uniform loading distributed on a circle are obtained by exact integral expressions. The numerical results are performed to show the anisotropic effect with isovalue curves of stress. To cite this article: C. Ruimy, M. Dahan, C. R. Mecanique 330 (2002) 469–473. 相似文献